ACTFLOW™ | Non-Solvent, Functional Liquid Acrylic Polymer

Product Description

ACTFLOW™ is a non-solvent type of functional and reactive acrylic polymer created using molecular weight control technology. As a non-solvent polymer, it is environmentally friendly and has excellent room-temperature fluidity, making it suitable for use as a plasticizer substitute, modifier, or additive.

ACTFLOW™ | Non-Solvent, Functional Liquid Acrylic Polymer

Features provided by ACTFLOW™

  • Low-temperature flexibility
  • Heat resistance
  • Weather resistance
  • Storage stability
  • Thermal sol formation properties
  • Impact resistance

Features

  • Non-solvent type
  • Transparent liquid with excellent compatibility and dispersibility
  • Acrylic polymer with terminal functional groups
  • Can be crosslinked by mixing with curing agent
  • Molecular weight, and functional group amounts and types, can be controlled
  • Functionality can be achieved as modifiers added to various resins
Principal molecular structure
Principal molecular structure

Structural model of ACTFLOW™

Terminal functional group type

A functional group is introduced at each molecular terminus. This is effective when the number of functional groups has to be adjusted independently of the molecular weight.

Terminal functional group type

Functional-group-copolymerization type

Functional groups can be introduced relatively easily by copolymerizing monomers with functional groups. In addition, this is effective for increasing the number of functional groups in a molecule.

Functional-group-copolymerization type

Molecular-terminus and functional-group-copolymerization type

This combines the advantages of the molecular-terminus type and the copolymerization type. Combinations of different functional groups are also possible, enabling achievement of even higher functionality.

Molecular-terminus and functional-group-copolymerization type

Terminal-functional-group-type multimerization

ACTFLOW™'s molecular structure, characterized by multiple highly reactive terminal functional groups and a hyper branching structure, presents advantages for crosslinking, compatibilizing, and thermosetting resin components.

Terminal-functional-group-type multimerization

Applications

  • Resist modifiers
  • Various resin modifiers: Acrylic, urethane, polyvinyl chloride (PVC), olefin, ABS, EVA, polyacetal, cellulose

Application case studies

As a non-solvent liquid resin, ACTFLOW™ is used as a modifier in various applications.

Plasticizers and softeners for various resins

ACTFLOW™ is useful as a plasticizer for soft PVC. In particular, it has an excellent balance of storage stability, thermal sol formation properties, and low-temperature perspiration, especially in the PVC sol process. In addition, it has high compatibility not only with PVC but with resins such as EVA and acrylic, and is effective for improving the low-temperature flexibility of acrylic sheets.

Additives and modifiers

ACTFLOW™ has a proven track record as a modifier of olefin resins and ABS resins. For ABS resins, it is effective as an impact resistance modifier. It is also effective for modifying polyacetal and cellulose resins.

Modifier for Photolithography

ACTFLOW™ is useful as an additive to improve the alkaline washability of resist materials such as those used in photolithography, as well as for enhancing the removal of residues and debris. It is also useful as an additive for color filters and dry film resists.

Base resin for films and sheets

The excellent durability and transparency of the acrylic backbone make ACTFLOW™ useful as a base resin for films and sheets. It is particularly useful as a base resin for thermoplastic acrylic urethanes, and thermosetting acrylic silyl and acrylic urethanes.

Base polyol for polyurethane resin

Using a multifunctional acrylic polyol, ACTFLOW™ is useful as a polyol component and/or crosslinking component for urethane films and sheets. It is effective for modifying and improving the physical properties of various urethane resins, such as sealants, adhesives, urethane acrylate oligomers, paints, coating agents, films, sheets, and foams, enabling introduction of acrylic backbones with high heat resistance and weather resistance to urethane resins. Especially when used in combination with hexamethylene diisocyanate prepolymers, films and sheets with excellent weather and heat resistance can be obtained.

Grade (product no.)

*Can be scrolled horizontally

Product no. Main backbone Functional group
Morphology
Structural diagram  Functional group equivalent content (g/eq) Mean molecular weight Viscosity at 25°C (mPa-s)
UMM-1001 MA Hydroxyl group
One terminus
600 1,000 8,000 to 13,500
UT-1001 2EHA 1,2-diol
One terminus
970 3,500 2,000 to 5,000
CB-3060 2EHA Carboxyl
Multifunctional
940 3,000 4,500 to 8,500
CB-3098 2EHA Carboxyl
Multifunctional
570 3,000 10,000 to 20,000
CBB-3098 BA Carboxyl
Multifunctional
570 3,000 12,500 to 20,500
NE-1000 BA -Si(OCH3)3
One terminus
620 3,000 700 to 1,300
NE-3000* MMA -Si(OCH3)3
Multifunctional
370
(converted to solid con)*
5,000 1,500 to 5,000
K-009 Acrylic Nonfunctional   No functional groups 250,000 Powder
  • Note: NE-3000 contains 30% ethyl acetate. In external appearance, ACTFLOW™ is a clear colorless liquid.
  • Note: The above properties and values are for reference only and are subject to change without notice.

Application examples

K-009, a flexibilizer for polylactic acid (PLA)*
K-009, a flexibilizer for polylactic acid (PLA)
K-009, a flexibilizer for polylactic acid (PLA)

*Can be scrolled horizontally

No. K-009 (wt%) Modulus of elasticity (N/mm2) Elongation (%) Tg (°C) Tm (°C)
1-1 0 4,598 3 56 160
1-2 20 3,948 28 57 161
1-3 40 2,766 43 57 162
1-4 60 1,879 58 57 162
1-5 100 126 92 21 None.
  • * PLA: The thickness of 4032D film (NatureWorks LLC) is in all cases adjusted to approximately 200 μm.

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  • Note: The data listed are for reference only and are not standard values.
    In addition, there is no guarantee that the listed uses will not infringe on any patents.